Determination of low phosphorus content in heat-resisting nickel alloys by ICP-MS method

Yakimovitch P.V., Alekseev A.V., Min P.G.
UDC
543.51:669.1
DOI
10.18577/2307-6046-2014-0-10-2-2
Article PDF (Russian) (567.18 KB)
How to cite
Yakimovitch P.V., Alekseev A.V., Min P.G. Determination of low phosphorus content in heat-resisting nickel alloys by ICP-MS method // Proceedings of VIAM. 2014. No. 10. DOI: 10.18577/2307-6046-2014-0-10-2-2. URL: https://test.viam.ru/en/journal/2014/10/2
Abstract

Determination of phosphorus mass content (less than 0,001% wt.) in standard specimens of nickel alloys was carried out by mass-spectrometry method with inductively coupled plasma (ICP-MS). Spectral interferences were eliminated using mathematical correction equation. The technique of sample dissolving and its preparation for analysis was presented. Relative standard deviation doesn’t exceed 0,05 in the concentration range of 0,0006–0,0065% wt. A detection limit in solution is 0,7μg/l, a detection limit in alloys – 0, 0004 % wt.

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