Crevice corrosion of aluminum alloys and stainless steel in marine water

Varchenko E.A., Kurs M.G.
Varchenko E.A., Kurs M.G. Crevice corrosion of aluminum alloys and stainless steel in marine water // Proceedings of VIAM. 2018. No. 7. DOI: 10.18577/2307-6046-2018-0-7-96-105. URL: https://test.viam.ru/en/journal/2018/7/11
Keywords
crevice corrosion, full-scale marine tests, aluminum alloys, stainless steels, biofouling, metallographic analysis.
Abstract

The results of a study of the susceptibility to crevice corrosion of aluminum alloys AMg6, D16-T and stainless steel 08X17 in tests in the natural sea water of the Black Sea are presented. The estimation of changes in appearance of samples, metallographic analysis and estimation of the degree of biofouling is carried out. Physico-chemical indicators of sea water, including those determined by capillary electrophoresis, are presented. The analysis of corrosion resistance tests in seawater, the features of the methodology for slit corrosion testing, and the mechanism of crevice corrosion formation are presented.

Reference list
  1. Kablov E.N. Materialy novogo pokoleniya – osnova innovatsij, tekhnologicheskogo liderstva i natsionalnoj bezopasnosti Rossii [Materials of new generation – basis of innovations, technological leadership and national security of Russia] // Intellekt i tekhnologii. 2016. №2 (14). S. 16–21.
  2. Kablov E.N. Materialy i tekhnologii VIAM dlya «Aviadvigatelya» [Materials and VIAM technologies for «Aviadvigatel»] // Permskie aviatsionnye dvigateli: inform. byul. 2014. №S. S. 43–47.
  3. Kablov E.N., Nikiforov A.A., Demin S.A., Chesnokov D.V., Vinogradov S.S. Perspektivnye pokrytiya dlya zashchity ot korrozii uglerodistykh stalej [Perspective coverings for corrosion protection of carbon steels] // Stal. 2016. №6. S. 70–81.
  4. Kablov E.N., Shchetanov B.V., Grashhenkov D.V., Shavnev A.A., Nyafkin A.N. Metallomatrichnye kompozicionnye materialy na osnove Al–SiC [Metalmatrix composite materials on the basis of Al–SiC] // Aviacionnye materialy i tehnologii. 2012. №S. S. 373–380.
  5. Rozenfeld I.L. Korroziya i zashchita metallov [Corrosion and protection of metals]. M.: Metallurgiya, 1969. 448 s.
  6. Zajtsev A.N., Suzdaltseva E.V. K voprosu o korrozii trub goryachego vodosnabzheniya iz nerzhaveyushchej stali [To question of corrosion of pipes of hot water supply from stainless steel] // Sistemnye tekhnologii. 2017. №23. S. 4–14.
  7. Kablov E.N., Startsev O.V., Krotov A.S., Kirillov V.N. Klimaticheskoe starenie kompozitsionnykh materialov aviatsionnogo naznacheniya. II. Relaksatsiya iskhodnoj strukturnoj neravnovesnosti i gradient svojstv po tolshchine [Climatic aging of composite materials of aviation assignment. II. Relaxation of initial structural non-equilibrium and gradient of properties on thickness] // Deformatsiya i razrushenie materialov. 2010. №12. S. 40–46.
  8. Kirillov V.N., Efimov V.A. Problemy issledovaniya klimaticheskoj stojkosti aviatsionnykh nemetallicheskikh materialov [Problems of research of climatic firmness of aviation non-metallic materials] // 75 let. Aviatsionnye materialy. Izbrannye trudy «VIAM» 1932–2007: yubil. nauch.-tekhnich. sb. M.: VIAM, 2007. S. 379–388.
  9. Kablov E.N., Grashchenkov D.V., Shchetanov B.V., Shavnev A.A., Nyafkin A.N. i dr. Metallicheskie kompozitsionnye materialy na osnove Al‒SiC dlya silovoj eletroniki [Problems of research of climatic firmness of aviation non-metallic materials] // Mekhanika kompozitsionnykh materialov i konstruktsij. 2012. T.18. №3. S. 359–368.
  10. Kablov E.N., Startsev O.V., Medvedev I.M. Obzor zarubezhnogo opyta issledovanij korrozii i sredstv zashhity ot korrozii [Review of international experience on corrosion and corrosion protection] // Aviacionnye materialy i tehnologii. 2015. №2 (35). S. 76–87. DOI: 10.18577/2071-9140-2015-0-2-76-87.
  11. Kurs M.G., Karimova S.A. Naturno-uskorennye ispytaniya: osobennosti metodiki i sposoby ocenki korrozionnyh harakteristik alyuminievyh splavov [Salt-accelerated outdoor corrosion testing: methodology and evaluation of corrosion susceptibility of aluminum alloy] // Aviacionnye materialy i tehnologii. 2014. №1. S. 51–57. DOI: 10.18577/2071-9140-2014-0-1-51-57.
  12. Sinyavskij B.S., Kalinin V.D. Korroziya i sposoby zashchity alyuminievykh splavov v morskoj vode sootvetstvenno ikh sostavu i structure [Corrosion and ways of protection of aluminum alloys in sea water according to their structure and structure] // Zashchita metallov. 2005. T. 41. №4. S. 347–359.
  13. Belous V.Ya., Gurvich L.Ya., Erofeeva V.L. i dr. Shchelevaya korroziya nerzhaveyushchikh stalej v atmosphere [Crevice corrosion of stainless steels in the atmosphere] // Zashchita metallov. 1995. T. 31. №2. S. 184–190.
  14. Kablov E.N. Innovacionnye razrabotki FGUP «VIAM» GNC RF po realizacii «Strategicheskih napravlenij razvitiya materialov i tehnologij ih pererabotki na period do 2030 goda» [Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030»] // Aviacionnye materialy i tehnologii. 2015. №1 (34). S. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  15. Sinyavskij V.S., Valkov V.D., Kalinin V.D. Korroziya i zashchita alyuminievykh splavov. 2-e izd. [Corrosion and protection of aluminum alloys. 2nd ed.]. M.: Metallurgiya, 1986. 368 s.
  16. Morskaya korroziya: spravochnik [Sea corrosion: directory]. M.: Metallurgiya, 1983. 512 s.
  17. Syrkin A.M., Molyavko M.A., SHevlyakov F.B. Osnovy elektrokhimicheskikh protsessov: ucheb. posobie [Bases of electrochemical processes: manual]. Ufa: Izd-vo UGNTU, 2009. 127 s.
  18. Feoktistova M.V. Vliyanie khimicheskogo sostava i strukturnykh faktorov na korrozionnuyu stojkost nizkolegirovannykh stalej v vodnykh sredakh: avtoref. diss. … kand. tekhn. nauk [Influence of chemical composition and structural factors on corrosion resistance of low-alloy steels in water environments: thesis, Cand. Sc. (Tech.)]. M., 2018. 28 s.
  19. GOST 9.909–86. Metally, splavy, pokrytiya metallicheskie i nemetallicheskie neorganicheskie. Metody ispytanij na klimaticheskikh ispytatelnykh stantsiyakh [State Standard 9.909–86. Metals, alloys, coverings the metal and nonmetallic inorganic. Test methods on climatic test stations]. M.: Izd-vo standartov, 1986. 20 s.
  20. ISO 8565:2011. Metally i splavy. Ispytanie na atmosfernuyu korroziyu. Obshchie trebovaniya [ISO 8565:2011. Metals and alloys. Testing for atmospheric corrosion. General requirements]. Shvejtsariya, Zheneva: ISO, 2011. 5 s.
  21. ASTM G0078-01. Rukovodstvo po provedeniyu ispytanij na shchelevuyu korroziyu nerzhaveyushchikh splavov na osnove zheleza i nikelya v morskoj vode i drugikh khloridsoderzhashchikh vodnykh sredakh [ASTM G0078-01. The guide to carrying out tests for crevice corrosion of corrosion-proof ferrous alloys and nickel in sea water and others chloride containing water environments]. SShA: ASTM, 2001. 7 s.
  22. ASTM G0048-03. Metody ispytanij dlya opredeleniya soprotivleniya tochechnoj i shchelevoj korrozii nerzhaveyushchikh stalej i splavov s ispolzovaniem rastvora khlorida zheleza [ASTM G0048-03. Test methods for determination of resistance of pitting and crevice corrosion of stainless steels and alloys with use of solution of ferric chloride]. SShA: ASTM, 2003. 11 s.
  23. Garner A. Crevice Corrosion of stainless steels in seawater: correlation of field data with laboratory ferric chloride tests // Corrosion. 1981. Vol. 37. No. 3. Р. 178–184.