Application of the glow discharge high resolution mass spectrometry method in analysis of nickel alloys

Alekseev A.V., Yakimovitch P.V.
UDC
543.51:669.245
DOI
10.18577/2307-6046-2020-0-8-101-108
Article PDF (Russian) (724.9 KB)
How to cite
Alekseev A.V., Yakimovitch P.V. Application of the glow discharge high resolution mass spectrometry method in analysis of nickel alloys // Proceedings of VIAM. 2020. No. 8. DOI: 10.18577/2307-6046-2020-0-8-101-108. URL: https://test.viam.ru/en/journal/2020/8/10
Keywords
high-resolution mass-spectrometry, GD-MS, nickel alloys, determination of harmful impurities, analysis of nickel alloys.
Abstract

The content of 19 elements (B, Al, Si, P, Ti, Cr, Fe, Co, Ni, Zr, Nb, Mo, Hf, Ta, W, Se, As, Pb, Bi) in the samples of nickel alloys was determined by high resolution glow discharge mass spectrometry. The selection of analysis conditions is given. Spectral interference is eliminated by the use of high resolution. The correctness of the results obtained is confirmed by analysis of a certified standard samples of nickel alloy. The range of determined concentrations: 0,000002–53,4% (of the mass), the relative standard deviation does not exceed 0,05.

Reference list
  1. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  2. Kablov E.N., Bondarenko Yu.A., Echin A.B. Development of technology of cast superalloys directional solidification with variable controlled temperature gradient. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 24–38. DOI: 10.18577/2071-9140-2017-0-S-24-38.
  3. Petrushin N.V., Ospennikova O.G., Svetlov I.L. Single-crystal Ni-based superalloys for turbine blades of advanced gas turbine engines. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 72−103. DOI: 10.18577/2071-9140-2017-0-S-72-103.
  4. Kablov E.N., Ospennikova O.G., Svetlov I.L. Highly efficient cooling of GTE hot section blades. Aviacionnye materialy i tehnologii, 2017, no. 2 (47), pp. 3–14. DOI: 10.18577/2071-9140-2017-0-2-3-14.
  5. Kablov E.N., Chabina E.B., Morozov G.A., Muravskaya N.P. Conformity assessment of new materials using high-level CRM and MI. Kompetentnost, 2017, no. 2, pp. 40–46.
  6. State Standard 6689.5–92. Nickel, nickel and copper-nickel alloys. Methods for the determination of iron. Moscow: Gosstandart of Russia. 1992, pp. 1–5.
  7. State Standard 6689.12–92. Nickel, nickel and copper-nickel alloys. Methods for the determination of magnesium. Moscow: Gosstandart of Russia, 1992, pp. 1–5.
  8. State Standard 6689.6–92. Nickel, nickel and copper-nickel alloys. Methods for the determination of manganese. Moscow: Gosstandart of Russia, 1992, pp. 9–11.
  9. Dvoretskov R.M., Karachevtsev F.N., Zagvozdkina T.N., Mechanic E.A. Determination of alloying elements of nickel alloys for aviation use by the AES-ICP method in combination with microwave sample preparation. Zavodskaya laboratoriya. Diagnostika materialov, 2013, vol. 79, no. 9, pp. 6–9.
  10. ASTM E2594-09. Standard Test Method for Analysis of Nickel Alloys by Inductively Coupled Plasma Atomic Emission Spectrometry. 2014, pp. 1–9.
  11. Hu J., Wang H. Determination of Trace Elements in Super Alloy by ICP-MS. Mikrochimica Acta, 2001, vol. 137, pp. 149–155.
  12. Letov A.F., Karachevtsev F.N., Zagvozdkina T.N. Development the set of methods measurements of the chemical composition of nickel-based alloys. Trudy VIAM, 2018, no. 8 (68), paper no. 09. Available at: http://www.viam-works.ru (accessed: March 23, 2020). DOI: 10.18577/2307-6046-2018-0-8-89-97.
  13. Pupyshev A.A., Epova E.N. Spectral interference of polyatomic ions in the method of mass spectrometry with inductively coupled plasma. Analitika i kontrol, 2001, vol. 5, no. 4, pp. 335–369.
  14. ASTM F2405-04. Standard Test Method for Trace Metallic Impurities in High Purity Copper by High-Mass-Resolution Glow Discharge Mass Spectrometer, 2011. pp. 1–5.
  15. Yakimovich P.V., Alekseev A.V. Determination of sulfur in casting heat-resistant nickel alloys by GD-MS. Trudy VIAM, 2020, no. 1, paper no. 11. Available at: http://www.viam-works.ru (accessed: March 23, 2020). DOI: 10.18557/2307-6046-2020-0-1-101-108.