Improvement of properties of fenolformaldehidny adhesives when updating by their polyvinylacetals

Lukina N.F., Kotova E.V., Petrova A.P., Isaev A.Yu.
Lukina N.F., Kotova E.V., Petrova A.P., Isaev A.Yu. Improvement of properties of fenolformaldehidny adhesives when updating by their polyvinylacetals // Proceedings of VIAM. 2022. No. 7. DOI: 10.18577/2307-6046-2022-0-7- 27-36. URL: https://test.viam.ru/en/journal/2022/7/3
Keywords
adhesive, fenolformaldegidny oligomer, resol, novolak, adhesive bond, polyvinylacetal, lap shear strength, influence of artificial factors
Abstract

Properties of not modified fenolformaldegidny adhesives, their structure and assignment are shown. Examples of adhesives on the basis of fenolformaldegidny resins, modified by polyvinylacetals are given. Improvement of properties of adhesives after their updating in such a way is shown. Strength characteristics of the adhesives joints executed with use of phenolopolyvinylacetal adhesives of brands VS-10T-U and VS-350 in initial condition and after artificial factors, simulating the operational are provided. It is shown that adhesives VS-10T-U and VS-350 provide operability of high-temperature tenzorezistors.

Reference list
  1. Kardashov D.A. synthetic adhesives. Ed. 3rd, revised. and additional Moscow: Khimiya, 1976, 504 p.
  2. Potsius A. Adhesives, adhesion, bonding technology. Trans. from Engl. St. Petersburg: Profession, 2007, 376 p.
  3. Aronovich D.A., Varlamov V.P., Voitovich V.A. et al. Bonding in mechanical engineering. Ed. G.V. Malysheva. Moscow: Nauka i tekhnologii, 2005, vol. 1, 544 p.
  4. Brodsky G.S., Chervinskaya M.A., Radchik L.D., Sheveleva R.A. Phenolic-polyvinyl acetal adhesives. Plasticheskiye massy, 1973, no. 6, pp. 29–30.
  5. Sinyakov S.D., Zastrogina O.B., Pavlyuk B.F. Compositions based on phenol-formaldehyde resins modified with polyvinyl acetals (review). Novosti materialovedeniya. Nauka i tekhnika, 2018, no. 1–2 (29), paper no. 08. Available at: http://materialsnews.ru (accessed: February 16, 2022).
  6. Shalun G.B., Surzhenko E.M. Laminated plastics. Leningrad: Khimiya, 1978, 232 p.
  7. Kablov E.N., Startsev V.O. Climatic aging of polymer composite materials for aviation purposes. I. Evaluation of the influence of significant factors of influence. Deformatsiya i razrusheniye materialov, 2019, no. 12, pp. 7–16.
  8. Lukina N.F., Petrova A.P., Kotova E.V. Heat-resistent adhesives used in aviation and space technique. Trudy VIAM, 2014, no. 3, paper no. 06. Available at: http://www.viam-works.ru (accessed: March 3, 2022). DOI: 10.18577/2307-6046-2014-0-3-6-6.
  9. Shuklina O.V., Lukina N.F. Properties of the new heat-resistant adhesive VS-10T-U. Klei. Germetiki. Tekhnologii, 2012, no. 5, pp. 8–9.
  10. Aviation materials: a reference book: in 13 vols. Ed. E.N. Kablov. Moscow: VIAM, 2019, vol. 10: Adhesives, sealants, rubbers, hydraulic fluids. Part 1: Adhesives, adhesive prepregs, 276 p.
  11. Lukina N.Ph., Petrova A.P., Muhametov R.R., Kogtjonkov A.S. New developments in the field of adhesive aviation materials. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 452–459. DOI: 10.18577/2071-9140-2017-0-S-452-459.
  12. Kablov E.N. The role of fundamental research in the creation of new generation materials. Reports of the XXI Mendeleev Congress on General and Applied Chemistry: in 6 vols. St. Petersburg, 2019, vol. 4, p. 24.
  13. Nikolaev E.V., Kirillov V.N., Skirta A.A., Grashhenkov D.V. Study of moisture transport rules and development of a standard on measurement of the diffusion coefficient and moisture content limit to evaluate mechanical properties of carbon fiber reinforced plastics. Aviacionnye materialy i tehnologii, 2013, no. 3, pp. 44–48.
  14. Kablov E.N., Laptev A.B., Prokopenko A.N., Gulyaev A.I. Relaxation of polymeric composite materials under the prolonged action of static load and climate (review). Part 1. Binders. Aviation materials and technologies, 2021, no. 4 (65), paper no. 08. Available at: http://www.journal.viam.ru (ассеssed: March 23, 2022). DOI: 10.18577/2071-9140-2021-0-4-70-80.
  15. Koloskova O.A., Barkovskaya N.P., Slavkin I.E., Kudryavtsev M.A. Application of high-temperature adhesive VS-350 in tensometry. Klei. Germetiki. Tekhnologii, 2019, no. 4, pp. 42–45.
  16. Laptev A.B., Barbotko S.L., Nikolaev E.V. The main research areas of the persistence properties of materials under the influence of climatic and operational factors. Aviacionnye materialy i tehnologii, 2017, no. S, pp. 547–561. DOI: 10.18577/2071-9140-2017-0-S-547-561.
  17. Murashov V.V. Application of the ultrasonic resonance method for detection of defects of glued constructions. Aviacionnye materialy i tehnologii, 2018, no. 1 (50), pp. 88–94. DOI: 10.18577/2071-9140-2018-0-1-88-94.
  18. Tsverava V.G., Rusin M.Yu., Nepovinnykh V.I., Himitsaev A.S. Analysis of the influence of accelerated climatic aging on the strength of adhesive joints. Klei. Germetiki. Tekhnologii, 2018, no. 8, pp. 28–31.