Modifying additives influence on the properties of SiO2–B2O3 system materials produced by sol-gel method

Lebedeva Yu.E., Shchegoleva N.E., Turchenko M.V., Volobueva T.M.
UDC
661.183.6
DOI
10.18577/2307-6046-2023-0-9-69-78
Article PDF (Russian) (909.57 KB)
How to cite
Lebedeva Yu.E., Shchegoleva N.E., Turchenko M.V., Volobueva T.M. Modifying additives influence on the properties of SiO2–B2O3 system materials produced by sol-gel method // Proceedings of VIAM. 2023. No. 9. DOI: 10.18577/2307-6046-2023-0-9-69-78. URL: https://test.viam.ru/en/journal/2023/9/6
Keywords
borosilicate system, sol-gel technology, carbon, starch, sugar, modification
Abstract

The work revealed the features of the influence of carbon-containing components on the synthesis of the borosilicate system by the sol-gel method. The influence of the nature (coal, starch, sugar) and the amount of the carbon-containing component on the gelation time, the behavior of the gel during the drying process and the retention of carbon in it were studied. The gelation time was 20; 312 and 2 hours for the sols of the SiO2–B2O3 system with starch, sugar and coal with starch, respectively. The gel with finely divided coal and dissolved in water and acid starch contained a maximal amount of carbon (24 %).

Reference list
  1. Evdokimov S.A., Shchegoleva N.E., Sorokin O.Yu. Ceramic materials aviation engineering (review). Trudy VIAM, 2018, no. 12 (72), paper no. 06. Available at: http://www.viam-works.ru (accessed: February 06, 2023). DOI: 10.18577/2307-6046-2018-0-12-54-61.
  2. Kuznetsov B.Yu., Sorokin O.Yu., Vaganova M.L., Osin I.V. Synthesis of model high-temperature ceramic matrices by the method of spark plasma sintering and the study of their properties for the production of composite materials. Aviacionnye materialy i tehnologii, 2018, no. 4 (53), pp. 37–44. DOI: 10.18577/2071-9140-2018-0-4-37-44.
  3. Zhitnyuk S.V. Oxygen-free ceramic materials for the space technics (review). Trudy VIAM, 2018, no. 8 (68), paper no. 08. Available at: http://www.viam-works.ru (accessed: February 06, 2023). DOI: 10.18577/2307-6046-2018-0-8-81-88.
  4. Voronov V.A., Chainikova A.S., Lebedeva Yu.E., Zhitnyuk S.V. Production, physico-mechanical and tribotechnical properties of hot-pressed carbon-ceramic composite material on the basis of silicon carbide. Aviation materials and technologies, 2022, no. 2 (67), paper no. 07. Available at: http://www.journal.viam.ru (accessed: August 03, 2023). DOI: 10.18577/2713-0193-2022-0-2-74-84.
  5. Wang L., Fan S., Sun H. et al. Pressure-less joining of SiCf/SiC composites by Y2O3–Al2O3–SiO2 glass: Microstructure and properties. Ceramic International, 2020, vol. 46, no. 17, pp. 27046–27056.
  6. Kablov E.N., Grashchenkov D.V., Isaeva N.V., Solntsev S.S., Sevastyanov V.G. High-Temperature Structural Composite Materials Based on Glass and Ceramics for Advanced Aircraft Products. Steklo i keramika, 2012, no. 4, pp. 7–11
  7. Babashov V.G., Varrik N.M., Maksimov V.G., Samorodova O.N. Oxide fiber coated with silicon carbide for producing composite materials. Aviation materials and technologies, 2021, no. 3 (64), paper no. 09. Available at: http://www.journal.viam.ru (accessed: February 06, 2023). DOI: 10.18577/2713-0193-2021-0-3-94-104.
  8. Wang X., Zhao J., Cui E. et al. Nano/microstructures and mechanical properties of Al2O3–WC–TiC ceramic composites incorporating graphene with different sizes. Materials Science & Engineering A, 2021, vol. 812, art. 141132.
  9. Cabet C. Review: Oxidation of SiC/SiC Composites in Low Oxidizing and High Temperature Environment. Materials Issues for Generation IV Systems. NATO Science for Peace and Security. Series B: Physics and Biophisics, 2008, pp. 351–366.
  10. Lee K.N., Fox D.S., Eldrige J.I. et al. Miller Upper temperature limit of Environmental Barrier Coatings based on mullite and BSAS. Journal of American Ceramic Society, 2003, vol. 86, no. 8, pp. 1299–1306.
  11. Jacobson N.S. Corrosion of Silicon-Based Ceramics in Combustion Environments. Journal of American Ceramic Society, 1993, vol. 76, no. 1, pp. 2–28.
  12. Kablov E.N., Chainikova A.S., Shchegoleva N.E., Grashchenkov D.V., Kovaleva V.S., Belyanchikov I.O. Synthesis, structure and properties of aluminosilicate glass ceramics modified with zirconium oxide. Inorganic Materials, 2020, vol. 56, no. 10, pp. 1123–1129.
  13. Alhaji A., Shoja Razavi R., Ghasemi A. et al. Modification of Pechini sol–gel process for the synthesis of MgO–Y2O3 composite nanopowder using sucrose-mediated technique. Ceramics International, 2017, vol. 43, pp. 2541–2548.
  14. Zanurin N.A., Johari J., Alias H. et al. Research progress of sol-gel ceramic coating: a review. Materials today: proceedings, 2022, vol. 48, part 6, pp. 1849–1854.
  15. Shabanova N.A., Sarkisov P.D. Fundamentals of the sol-gel technology of nanodispersed silica. Moscow: Akademkniga, 2006, 309 p.
  16. Tonooka K., Shimokawa K., Nishimura O. Preparation and luminescent properties of sol–gel derived SiO2–B2O3: Tb glass films. Solid State Ionics, 2002, vol. 151, is. 1–4, pp. 105–110.
  17. Grandi S., Tomasi C., Cassinelli V. et al. SiO2–B2O3 xerogels: The problem of boron leaching. Journal of Non-Crystalline Solids, 2012, vol. 358, is. 14, pp. 1631–1637.
  18. Medvedev E.F., Minko N.I. Features of the synthesis of silicate and borosilicate glass materials in an aqueous medium. Vestnik BSTU im. V.G. Shukhov, 2016, no. 10, pp. 156–165.
  19. Charles R.J. Metastable immiscibility of the B2O3–SiO2 system. Journal of American Ceramic Society, 1968, vol. 51, is. 1, pp. 220–225.
  20. Villegas M.A., Aparico M., Duran A. Thick sol-gel coatings based on the B2O3–SiO2 system. Journal of Non-Crystalline Solids. 1997, vol. 218, pp. 146–150.
  21. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.