Research of the process of hydrogen saturation of samples of titanium alloy type VT14

Shvetsova A.N., Eroshkin S.G.
Shvetsova A.N., Eroshkin S.G. Research of the process of hydrogen saturation of samples of titanium alloy type VT14 // Proceedings of VIAM. 2025. No. 1. DOI: 10.18577/2307-6046-2025-0-1-26-34. URL: https://test.viam.ru/en/journal/2025/1/3
Keywords
hydrogen determination, spectral analysis method, standard samples, hydrogen in titanium, chemical and electrochemical etching
Abstract

The wide application of titanium alloy parts in the aviation industry and the need to ensure high quality of their manufacture have led to necessity of the developing of new standard samples for determining and controlling the hydrogen content in titanium alloys. In this work the processes of hydrogenation of titanium alloy samples of the VT14 type by etching in a hydrochloric acid solution in the presence of fluorine ions and by electrochemical etching were studied. The material of standard sample blankes of the enterprise with different hydrogen content was manufactured. The hydrogen content in titanium alloys was measured using the emission spectral analysis method with spark excitation of the spectrum.

Reference list
  1. Kablov E.N. Trends and guidelines for innovative development of Russia: collection of scientific and information materials. 3rd ed., rev. and add. Moscow: VIAM, 2015, 720 p.
  2. Nochovnaya N.A., Bazyleva O.A., Kablov D.E., Panin P.V. Intermetallic alloys based on titanium and nickel. Ed. E.N. Kablov. 2nd ed., rev. and add. Moscow: VIAM, 2019, 316 p.
  3. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  4. Krasnov I.S., Lozhkova D.S., Dalin M.A. Evaluation of deficiency of titanium alloy forgings for probabilistic calculation of gas turbine engine disks fracture risk. Aviation materials and technologies, 2021, no. 2 (63), paper no. 12. Available at: http://www.journal.viam.ru (accessed: April 12, 2024). DOI: 10.18577/2713-0193-2021-0-2-115-122.
  5. Bondarenko Yu.A. Trends in the development of high-temperature metal materials and technologies in the production of modern aircraft gas turbine engines. Aviacionnye materialy i tehnologii, 2019, no. 2 (55), pp. 3–11. DOI: 10.18577/2071-9140-2019-0-2-3-11.
  6. Duyunova V.A., Pavlova T.V., Kashapov O.S., Chuchman O.V. Fatigue strength of forgings from VT6 alloy for parts of gas turbine engines and aircrafts. Aviation materials and technologies, 2023, no. 2 (71), paper no. 02. Available at: http://www.journal.viam.ru (accessed: April 12, 2024). DOI: 10.18577/2713-0193-2023-0-2-23-35.
  7. Kolachev B.A. Hydrogen embrittlement in non-ferrous metals. Moscow: Metallurgiya, 1966, 253 p.
  8. Duyunova V.A., Oglodkov M.S., Putyrskiy S.V., Kochetkov A.S., Zueva O.V. Modern technologies for melting titanium alloy ingots (review). Aviation materials and technologies, 2022, no. 1 (66), paper no. 03. Available at: http://www.journal.viam.ru (accessed: April 12, 2024). DOI: 10.18577/2713-0193-2022-0-1-30-40.
  9. Pivovarova L.N., Zakharova L.V., Fadeev A.V. Chemical treatment of titanium alloy surfaces. Modern titanium alloys and problems of their development. Moscow: VIAM, 2010, pp. 75–80.
  10. Industry Standard 1 90013–81. Titanium alloys. Brands. Moscow: Publ. house of standards, 1981, рр. 1–5.
  11. Kaganovich N.N., Shikhaleeva T.V. Hydrogenation of titanium alloys during etching. Metallovedenie i termicheskaya obrabotka metallov, 1963, no. 3, pp. 39–44.
  12. Kaganovich N.N. Titanium alloys for new technology. Moscow: Nauka, 1968, pp. 230–243.
  13. Livanov V.A., Bukhanov A.A., Kolachev B.A. Hydrogen in titanium. Moscow: GNTI, 1962, 246 p.
  14. Matyugina I.V., Pliner Yu.L., Usov V.N. Certified samples for spectral determination of hydrogen in titanium alloys. Zhurnal prikladnoy spektroskopii, 1972, vol. XVII, is. 1, pp. 13–16.
  15. Matyugina I.V., Pliner Yu.L., Shikhaleeva T.V., Usov V.N. Saturation of certified samples for spectral analysis of VT14 alloy with hydrogen. Trudy VNIISO, 1970, is. VI, pp. 62–66.
  16. Reznicenko V.A. Titanium and its alloys. Metallothermy and electrochemistry of titanium. Moscow: Publ. House of the USSR Academy of Sciences, 1961, 266 р.
  17. Straumanis M.E., Chem P.C. The Mechanism and Rate of Dissolution of Titanium in Hydrofluoric Acid. Journal of Electrochemical Society, 1951, vol. 98, no. 6, p. 63.