Ion-plasma heat-resistant coatings with high resistance to sulfide-oxide corrosion

Budinovskiy S.A., Benklyan A.S., Movenko D.A., Tatarnikov S.V.
UDC
629.7.023.224
DOI
10.18577/2307-6046-2025-0-9-77-89
Article PDF (Russian) (1.03 MB)
How to cite
Budinovskiy S.A., Benklyan A.S., Movenko D.A., Tatarnikov S.V. Ion-plasma heat-resistant coatings with high resistance to sulfide-oxide corrosion // Proceedings of VIAM. 2025. No. 9. DOI: 10.18577/2307-6046-2025-0-9-77-89. URL: https://test.viam.ru/en/journal/2025/9/6
Keywords
ion-plasma technology, heat-resistant nickel alloys, ion-plasma coatings, isothermal heat resistance, sulfide-oxide corrosion
Abstract

The paper presents the results of heat resistance testing of ZhS32 alloy samples with serial ion-plasma heat-resistant and corrosion-resistant coatings. The tests demonstrated heat resistance at 1150 °C for 400 h and resistance to sulfide-oxide corrosion at 750 and 850 °C for 30 cycles. According to the test results, the coatings SDP-42 + VSDP-16 and VSDP-3 + VSDP-16 exhibit the highest set of protective properties. These coatings prevent diffusion of sulfur and chlorine from the surface into the inner layers of the heat-resistant alloy. The above mentioned coatings out-perform the standard corrosion-resistant coating SDP-1T + VSDP-13 under test conditions.

Reference list
  1. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–34. DOI: 10.18577/2071-9140-2015-0-1-3-34.
  2. Kablov E.N., Muboyadzhyan S.A. Erosion-resistant coatings for compressor blades of gas turbine engines. Elektrometallurgiya, 2016, no. 10, pр. 23–38.
  3. Muboyadzhyan S.A., Kablov E.N., Ion etching and surface modification of critical machine parts in vacuum-arc plasma. Vestnik Moskovskogo gosudarstvennogo tekhnicheskogo universiteta im. N.E. Baumana. Ser.: Mashinostroenie, 2011, no. SP2, рр. 149–163.
  4. Doronin O.N., Artemenko N.I., Stekhov P.A., Voronov V.A. Deposition of ceramic layers of heat protection coatings based on the system Gd2O3–ZrO2–HfO2 and Sm2O3–Y2O3–HfO2. Aviation materials and technologies, 2022, no. 3 (68), paper no. 10. Available at: http://www.journal.viam.ru (accessed: March 05, 2025). DOI: 10.18577/2713-0193-2022-0-3-108-119.
  5. Kablov E.N. Science as a branch of the economy. Science and Life, 2009, no. 10, рр. 6–10.
  6. Kablov E.N., Muboyadzhyan S.A. Heat-protective coatings with a ceramic layer of low thermal conductivity based on zirconium oxide for high-pressure turbine blades of promising gas turbine engines. Modern achievements in the field of creating promising non-metallic composite materials and coatings for aviation and space technology: Reports of Sci. and Tech. Conf. Moscow: VIAM, 2015, p. 3.
  7. Doronin O.N., Gorlov D.S., Azarovsky E.N., Kochetkov A.S. Study of the structure and properties of a heat-resistant coating at high-temperature deformation of samples from titanium intermetallic alloy. Aviation materials and technology, 2021, no. 1 (62), paper no. 06. Available at: http://www.journal.viam.ru (accessed: March 05, 2025). DOI: 10.18577/2713-0193-2021-0-1-61-70.
  8. Batraev I.S., Rybin D.K., Ivanyuk K.V., Ulianitsky V.Yu., Shtertser A.A. Wear resistant detonation coatings based on tungsten carbide for aviation products. Aviation materials and technologies, 2022, no. 1 (66), paper no. 08. Available at: http://www.journal.viam.ru (ассеssed: March 05, 2025). DOI: 10.18577/2713-0193-2022-0-1-92-109.
  9. Goncharov B.E., Sipatov A.M., Cherkashneva N.N., Pleskan A.Yu., Samokhvalov N.Yu., Vaganova M.L., Sorokin O.Yu., Solntsev St.S., Evdokimov S.A. Studies of thermal shock resistance of an anti-oxidation coating for a multi-layered ceramic composite. Aviation materials and technologies, 2021, no. 4 (65), paper no. 06. Available at: http://www.journal.viam.ru (accessed: March 05, 2025). DOI: 10.18577/2713-0193-2021-0-4-51-58.
  10. Aleksandrov D.A., Muboyadzhyan S.A., Zhuravleva P.L., Gorlov D.S. Investigation of the effect of surface preparation and ion-assisted deposition on the structure and properties of erosion-resistant ion-plasma coating. Trudy VIAM, 2018, no. 10 (70), paper no. 08. Available at: http://www.viam-works.ru (accessed: March 05, 2025). DOI: 10.18577/2307-6046-2018-0-10-62-73.
  11. Muboyadzhyan S.A., Lutsenko A.N., Aleksandrov D.A., Gorlov D.S. Research of possibility of increase of office characteristics of compressor blades of GTE by method of ionic modifying of surface. Trudy VIAM, 2013, no. 1, paper no. 02. Available at: http://viam-works.ru (accessed: March 05, 2025).
  12. Muboyadzhyan S.A. Industrial ion-plasma equipment for applying protective coatings. Entsiklopediya inzhenera-khimika, 2012, no. 5, pp. 34–41.
  13. Galoyan A.G., Muboyadzhyan S.A., Egorova L.P., Bulavinceva E.E. Corrosion-resistant coating for protection of GTE details made of high-strength maraging constructional steel with operating temperature up to 450°C. Trudy VIAM, 2014, no. 6, paper no. 03. Available at: http://www.viam-works.ru (accessed: March 05, 2025). DOI: 10.18577/2307-6046-2014-0-6-3-3.
  14. Shchepilov A.V., Muboyadzhyan S.A., Gorlov D.S., Konnova V.I. Investigation of the ion-plasma coatings influence on damping capacity of «alloy-coating» composition during testing on vibrodynamic bench. Trudy VIAM, 2015, no. 4, paper no. 8. Available at: http://www.viam-works.ru (accessed: March 05, 2025). DOI: 10.18577/2307-6046-2015-0-4-8-8.
  15. Aleksandrov D.A., Muboyadzhyan S.A., Gorlov D.S. reinforcing properties of ion-plasma coatings using plasma assisted deposition. Trudy VIAM, 2015, no. 7, paper no. 07. Available at: http://www.viam-works.ru (accessed: March 05, 2025). DOI: 10.18577/2307-6046-2015-0-7-7-7.
  16. Muboyadzhyan S.A., Aleksandrov D.A., Gorlov D.S. Nanolayer strengthening coverings for protection of steel and titanic compressor blades of GTE. Aviacionnye materialy i tehnologii, 2011, no. 3, pp. 3–8.
  17. Muboyadzhjan S.A., Galoyan A.G. Complex thermodiffusion heat resisting coatings for carbon-free hot strength alloys on nickel basis. Aviacionnye materialy i tehnologii, 2012, no. 3, pp. 25–30.
  18. Muboyadzhyan S.A., Aleksandrov D.A., Gorlov D.S., Egorova L.P., Bulavinceva E.E. Protective and strengthening ion-plasma coverings for blades and other responsible details of the GTE compressor. Aviacionnye materialy i tehnologii, 2012, no. S, pp. 71–81.
  19. Azarovskij E.N., Mubojadzhjan S.A. Modifying of surface of details from constructional steels in vacuum and arc plasma of titanium. P. I. Aviacionnye materialy i tehnologii, 2013, no. 3, pp. 20–25.
  20. Azarovskij E.N., Mubojadzhjan S.A. Modifying of surface of details from constructional steels in vacuum and arc plasma of titanium. P. II. Aviacionnye materialy i tehnologii, 2014, no. 1, pp. 3–11. DOI: 10.18577/2071-9140-2014-0-1-3-11.
  21. Galoyan A.G., Muboyadzhyan S.A., Kashin D.S. Thermal diffusion processes for saturation of internal surface of GTE turbine blades made of advanced high temperature superalloys with refractory elements and carbon. Aviacionnye materialy i tehnologii, 2014, no. S5, pp. 45–55. DOI: 10.18577/2071-9140-2014-0-s5-45-55.
  22. Alexandrov D.A., Muboyadzhyan S.A., Gayamov A.M., Gorlov D.S. Studies of heat resistance and kinetics of elemental composition of VT41 titanium alloy with heat-resistant coatings. Aviacionnye materialy i tehnologii, 2014, no. S5, pp. 61–66. DOI: 10.18577/2071-9140-2014-0-s5-61-66.
  23. Muboyadzhyan S.A., Gorlov D.S., Shchepilov A.A., Konnova V.I. Study of damping capacity of ion-plasma coatings. Aviacionnye materialy i tehnologii, 2014, no. S5, pp. 67–72. DOI: 10.18577/2071-9140-2014-0-s5-67-72.
  24. Galoyan A.G., Muboyadzhyan S.A., Kashin D.S. Termodiffusion barrier formation under vacuum cementation process on rhenium and rhenium-ruthenium comprising nickel based superalloys. Aviacionnye materialy i tehnologii, 2015, no. 3 (36), pp. 27–37. DOI: 10.18577/2071-9140-2015-0-3-27-37.
  25. Budinovsky S.A., Petrushin N.V., Benklyan A.S., Elyutin E.S. Protection of heat-resistant nickel-rhenium-ruthenium alloy VZhM10 from oxidation in the temperature range of 1150‒1300 °C. Electrometallurgiya, 2024, no. 3, pp. 24–31. DOI: 10.31044/1684-5781-2024-0-3-24-31.
  26. Budinovsky S.A., Azarovsky E.N., Benklyan A.S. Protection of VZhM4 alloy from corrosion in the temperature range of 850‒1050 °C. Electrometallurgiya, 2023, no. 6, pp. 15–24. DOI: 10.31044/1684-5781-2023-0-6-15-24.
  27. Kosmin A.A., Budinovskiy S.A., Muboyadzhyan S.A. Heat and corrosion resistant coating for working turbine blades from promising high-temperature alloy VZhL21. Aviacionnye materialy i tehnologii, 2017, no. 1 (46), pp. 17–24. DOI: 0.18577/2071-9140-2017-0-1-17-24.
  28. Smirnov A.A., Budinovsky S.A. Heat-resistant and heat-protective coatings for gas turbine engine blades made of nickel-based heat-resistant rhenium and rhenium-ruthenium containing alloys. New developments in the field of protective, heat-protective and hardening coatings for gas turbine engine parts: Reports of Sci.-Tech. Conf. Moscow: VIAM, 2016, p. 13.
  29. Movenko D.A., Zavodov A.V., Laptev A.B., Loshchinina A.O. Changes in the structure of VZhM-4 alloy during high-temperature salt corrosion at 750 °C. Metallovedenie i termicheskaya obrabotka metallov, 2024, no. 5 (827), pp. 22–29.
  30. Muboyadzhyan S.A. Protective coatings for hot gas turbine tract parts. Vse materialy. Entsiklopedicheskiy spravochnik, 2011, no. 3, pp. 26–30.
  31. Method for protecting gas turbine blades: pat. 2404286 Rus. Federation; appl. 22.10.09; publ. 20.11.10.
  32. Muboyadzhyan S.A. Industrial ion-plasma equipment for applying protective coatings. Entsiklopediya inzhenera-khimika, 2012, no. 5, pp. 34–41.
  33. Azarovskij E.N., Muboyadzhyan S.A. Surface modification of parts from structural steel in vacuum-arc titanium plasma. P. III. Aviacionnye materialy i tehnologii, 2015, no. 4 (37), pp. 29–37. DOI: 10.18577/2071-9140-2015-0-4-29-37.
  34. Gorlov D.S., Muboyadzhyan S.A., Shhepilov A.A., Aleksandrov D.A. The research of erosion resistance and heat resistance of the ion-plasma damping coatings. Aviacionnye materialy i tehnologii, 2016, no. 2, pp. 11–17. DOI: 0.18577/2071-9140-2016-0-2-11-17.