About possible destruction causes of vacuum melted PZlM-type solders

Galkin V.I., Golovkin P.A., Dvoretskov R.M., Galkin E.V.
Galkin V.I., Golovkin P.A., Dvoretskov R.M., Galkin E.V. About possible destruction causes of vacuum melted PZlM-type solders // Proceedings of VIAM. 2026. No. 4. DOI: 10.18577/2307-6046-2026-0-4-146-157. URL: https://test.viam.ru/en/journal/2026/4/12
Keywords
electrovacuum devices, solder wire, technical specifications, chemical composition, gold, copper, impurities, state diagrams, solubility, alloy structure ordering, degradation
Abstract

The study considers possible destruction causes of the PZlM-type solder wire made of gold-copper alloys used for soldering and assembling of components in electrovacuum devices. The possible causes of wire defects are impurities of rhodium and ruthenium, entering into the solder wire due to improper control of the chemical composition of the source materials, caused by the imperfection of the current regulatory documentation for solders and their components. It is proposed to carry out the output control of manufactured PZlM-type solders after at least 10 days, required for recrystallization and alignement of the material after preliminary annealing.

Reference list
  1. Onishchenko G.G., Kablov E.N., Ivanov V.V. Scientific and technological development of Russia in the context of achieving national goals: problems and solutions. Innovatsii, 2020, no. 6 (260), pp. 3–16.
  2. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  3. Cherepnin N.V. Vacuum properties of materials for electronic devices. Moscow: Sovetskoe radio, 1966, 352 p.
  4. Sviridov A.V., Afanasyev-Khodykin A.N., Galushka I.A. Corrosion resistance of the brazed joints of the GTE fuel manifolds, made with various brazing alloys. Trudy VIAM, 2021, no. 1 (95), pp. 23–33. Available at: http://www.viam-works.ru (accessed: April 25, 2025). DOI: 10.18577/2307-6046-2021-0-1-23-33.
  5. Kablov E.N., Ospennikova O.G., Cherednichenko I.V., Rezchikova I.I., Valeev R.A., Piskorskij V.P. Influence of Cu content to phase structure and magnetic properties of thermostable sintered magnets of Nd–Dy–Fe–Co–B and Pr–Dy–Fe–Co–B systems. Aviacionnye materialy i tehnologii, 2015, no. S2 (39), pp. 11–19. DOI: 10.18577/2071-9140-2015-0-S2-11-19.
  6. Fedorov I.A. Rhodium. 2nd ed. Moscow: Metallurgiya, 1970, 364 p.
  7. Zvyagintsev O.E. Refining of Gold, Silver, and Platinum Group Metals. 3rd ed., rev. and ad. Moscow: State Sc. and Tech. Pub. House of Literature on Ferrous and Non-Ferrous Metallurgy, 1945, 241 p.
  8. Method for the Selective Extraction of Palladium, Platinum, and Rhodium from Concentrates: pat. 2398898 C1 Rus. Federation; appl. 09.04.09; publ. 10.09.10.
  9. Kablov E.N., Kutyrev A.E., Vdovin A.I., Kozlov I.A., Afanasyev-Khodykin A.N. The research of possibility of galvanic corrosion in brazed connections used in aviation engine construction. Aviation materials and technologies, 2021, no. 4 (65), pp. 3–13. Available at: http://www.journal.viam.ru (accessed: April 25, 2025). DOI: 10.18577/2713-0193-2021-0-4-3-13.
  10. Naprienko S.A., Erak A.D., Afanasev-Khodykin A.N., Davidenko A.N. Structure variation and properties of soldered joints ВПр16 under various temperature exposures. Aviation materials and technologies, 2023, no. 1 (70), pp. 115–125. Available at: http://www.journal.viam.ru (accessed: April 25, 2025). DOI: 10.18577/2713-0193-2023-0-1-115-125.
  11. Dvoretskov R.M., Tikhonov М.М., Karachevtsev F.N., Kuko I.S. Determination of the chemical composition of heat-resistant alloys at various stages of additive manufacturing. Trudy VIAM, 2021, no. 6 (100), pp. 112–122. Available at: http://www.viam-works.ru (accessed: April 25, 2025). DOI: 10.18577/2307-6046-2021-0-6-112-122.
  12. Phase Diagrams of Binary Metallic Systems: A Handbook in 3 vols. Ed. N.P. Lyakishev. Moscow: Nauka, 1996, vol. 1, 992 p.
  13. Malyshev V.M., Rumyantsev D.V. Gold. Moscow: Metallurgiya, 1979, 288 p.
  14. Binary and Multicomponent Systems Based on Copper: A Handbook. Moscow: Nauka, 1979, 248 p.
  15. Phase Diagrams of Binary Metallic Systems: A Handbook in 3 vols. Ed. N.P. Lyakishev. Moscow: Nauka, 1996, vol. 3, book 1, 872 p.
  16. Suchkov D.I. Copper and Its Alloys. Moscow: Metallurgiya, 1966, 248 p.
  17. Phase Diagrams of Binary Metallic Systems: A Handbook in 3 vols. Ed. N.P. Lyakishev. Moscow: Nauka, 1996, vol. 2, 1028 p.
  18. Lainer D.I., Malysheva L.A., Luneva V.I. et al. On the Recrystallization Features of Copper of Varying Purity, Rolled with a High Degree of Deformation. Nauchnye Trudy institute «Giprotsvetmetobrabotka». Moscow: Metallurgiya, 1974, is 42: Metallurgy of Copper and Copper-Based Alloys, pp. 39–44.
  19. Bodyako M.N., Astapchik S.A., Yaroshevich G.B. Thermokinetics of Recrystallization. Minsk: Nauka i tekhnologiya, 1968, 252 p.
  20. Ugai Ya.A. General Chemistry: Textbook for Students of Chemical Specialized Universities. 2nd ed., rev. and ad. Moscow: Vysshaya Shkola, 1984, 440 p.
  21. Maltsev M.V. Metallography of Industrial Non-Ferrous Metals and Alloys. 2nd ed. Moscow: Metallurgiya, 1970, 364 p.
  22. Golovkin P.A. Improving the Quality of Oxygen-Free Copper Parts for Microwave Electrovacuum Devices. Technologiya mashinostroeniya, 2020, no. 5, pp. 34–41.
  23. Golovkin P.A. Influence of light shades in the material of oxygen-free copper rods on its vacuum density. Int. sc.-pract. conf. «Advanced mechanical engineering technologies». St. Petersburg, 2024, pp. 298–304.
  24. State Standard 10988–2016. Oxygen-free copper rods for the vacuum tube industry. Specifications. Moscow: Standartinform, 2017, 15 p.
  25. Novikov I.I., Fonarev G.S. On the dependence of the plasticity of polycrystalline copper on temperature. Metallurgy of non-ferrous metals and alloys. Moscow: Nauka, 1972, pp. 135–140.