Aluminum oxide-based catalyst carriers

Bespalov A.S.
Bespalov A.S. Aluminum oxide-based catalyst carriers // Proceedings of VIAM. 2026. No. 6. DOI: 10.18577/2307-6046-2026-0-6-108-117. URL: https://test.viam.ru/en/journal/2026/6/10
Keywords
fibrous high-porous ceramic material, alumina fibers, gamma phase, catalyst, catalyst carrier, conversion
Abstract

Methods of preparation and main directions of application of carriers of heterogeneous catalysts based on aluminum oxide are considered. Some aspects of the use of highly porous ceramic materials based on oxide fibers are shown, revealing the prospects of using this class of material as carriers of catalysts and catalytically active substances. The high efficiency of using catalysts on carriers made of such materials in promising processes for producing synthesis gas from oxygen and carbon dioxide conversions of methane is shown.

Reference list
  1. Leffler W.L. Oil refining. 2nd ed., rev. trans. from Engl. Moscow: Olimp-Biznes, 2004, 224 p.
  2. Stiles A.B. Catalyst supports and supported catalysts. Theoretical and applied concepts. Boston: Butterworths publishers, 1987, 270 p. DOI: 10.1002/aic.690340129.
  3. Kapustin V.M., Ivanov A.V. Production of catalysts for oil refining and petrochemistry in Russia. Neftegaz.RU, 2023, no. 9 (141), p. 18. Available at: https://magazine.neftegaz.ru/articles/
  4. importozameshchenie/795285-proizvodstvo-katalizatorov-dlya-neftepererabotki-i-neftekhimii-v-rossii/Научная статья (accessed: November 01, 2025).
  5. Oil refineries of Russia and the CIS countries: a reference book. Moscow: OMT-Konsalt, 2018, 155 p.
  6. Catalog of oil refineries and gas processing plants (ORPs/GPPs). CIS LNG project facilities. Available at: https://clck.ru/TKVdn (accessed: November 01, 2025).
  7. Noskov A.S. Scientific and technical level of research and prospects for import substitution in the field of industrial catalysts. Vestnik RAN, 2022, vol. 92, no. 10, pp. 940–949.
  8. Bespalov A.S., Istomin A.V. Features of high-porous materials for use as carriers of catalytically active substances. Trudy VIAM, 2025, no. 8 (150), pp. 96–105. Available at: http://www.viam-works.ru (accessed: November 01, 2025). DOI: 10.18577/2307-6046-2025-0-10-96-105.
  9. Dzisko V.A., Ivanova A.S. Basic methods for obtaining active aluminum oxide. Izvestiya SO AN SSSR. Ser.: Chemical Sciences, 1985, no. 15, pp. 110–119.
  10. Ryabov V.D. Chemistry of Oil and Gas: Textbook for Univ. Moscow: Publ. House «Tekhnika» GUMA GRUPP, 2018, 288 p.
  11. Ptáček P. Strontium Aluminate – Cement Fundamentals, Manufacturing, Hydration, Setting Behaviour and Applications. Rijeka: In Tech, 2014. 350 p.
  12. Digne M., Raybaud P., Sautet P. et al. Atomic scale insights on chlorinated alumina surfaces. Journal of the American Chemical Society, 2008, vol. 130, pp. 11030–11039.
  13. Borutskiy P.N. Catalytic processes for producing branched hydrocarbons. St. Petersburg: Professional, 2010, 724 p.
  14. Knyazev A.V., Lavrov B.A. Modern technologies for the production of aluminum hydroxide raw materials for catalyst supports. Izvestiya Sankt-Peterburgskogo gosudarstvennogo tekhnologicheskogo instituta (Tekhnicheskogo universiteta), 2021, no. 59 (84), pp. 37–46. DOI: 10.36807/1998-9849-2021-59-85-37-46.
  15. Tagandurdyeva N., Narayev V.N., Postnov A.Yu., Maltseva N.V. Preparation of an alumina support for a hydrocarbon isomerization catalyst by rehydration of gibbsite thermal activation products. Izvestiya Sankt-Peterburgskogo gosudarstvennogo tekhnologicheskogo instituta (Tekhnicheskogo universiteta), 2018, no. 46 (72), pp. 16–21.
  16. Tambasova D.P., Lyubyakina P.N., Antonov D.O., Kovaleva E.G. Heterogeneous catalysts based on gamma-alumina with immobilized xylanase for the hydrolytic decomposition of xylan. Vestnik Yuzhno-Ural'skogo gosudarstvennogo universiteta. Ser.: Food and Biotechnology, 2021, vol. 9, no. 1, pp. 57–67. DOI: 10.14529/ food210107.
  17. Chan S.S., Wachs I.E., Murrell L.L. et al. Laser Raman characterization of tungsten oxide supported on alumina: influence of calcination temperatures. Journal of Catalysis, 1985, vol. 92, is. 1, pp. 1–10. DOI: 10.1016/0021-9517(85)90231-3.
  18. Kablov E.N. Innovative developments of FSUE «VIAM» SSC of RF on realization of «Strategic directions of the development of materials and technologies of their processing for the period until 2030». Aviacionnye materialy i tehnologii, 2015, no. 1 (34), pp. 3–33. DOI: 10.18577/2071-9140-2015-0-1-3-33.
  19. Savritskiy A.N., Marakhovskiy P.S., Salimov I.E., Babashov V.G. Examination of the dependence of thermal conductivity on the density of a low-density thermal and sound insulation material based on glass fibers. Aviation materials and technologies, 2025, no. 3 (80), pp. 149–160. Available at: http://www.journal.viam.ru (accessed: November 01, 2025). DOI: 10.18577/2713-0193-2025-0-3-149-160.
  20. Sudzhanskaya I.V., Lebedeva Yu.E., Vaganova M.L., Shchegoleva N.E. Parameters affecting on the ionic conductivity of solid electrolytes based on cerium dioxide. Trudy VIAM, 2025, no. 2 (144), pp. 60–73. Available at: http://www.viam-works.ru (accessed: November 01, 2025). DOI: 10.18577/2307-6046-2025-0-1-60-73.
  21. Bespalov A.S., Salimov I.E., Yudin A.V. Imparting highly hydrophobic properties to a high-porous ceramic material with low-concentration solutions of fluoroparaffin in a supercritical carbon dioxide environment. Aviation materials and technologies, 2025, no. 1 (78), pp. 39‒48. Available at: http://www.journal.viam.ru (accessed: October 27, 2025). DOI: 10.18577/2713-0193-2025-0-1-39-48.
  22. Buznik V.M., Babashov V.G., Bespalov A.S. et al. Fundamental Research to Improve and Expand the Application Areas of Highly Porous Ceramic Materials. The Role of Fundamental Research in the Implementation of Strategic Directions for the Development of Materials and Their Processing Technologies for the Period up to 2030: Proc. of the V All-Rus. Sci. and Tech. Conf. Moscow, 2019, pp. 18–39.
  23. Arutyunov V.S., Krylov O.V. Organic Chemistry: Oxidative Transformations of Methane: A Textbook for Univ. 2nd ed., cor. and rev. Moscow: Yurait, 2017, 371 p.
  24. Rodrigues L.M.T.S., Silva R.B., Rocha M.G.C. et al. Partial oxidation of methane on Ni and Pd catalysts: influence of active phase and CeO2 modification. Catalysis Today, 2012, vol. 197 (1), pp. 137–143.
  25. Zeng S., Zhang X., Fu X. et al. Co/CexZr1–xO2 solid-solution catalysts with cubic fluorite structure for carbon dioxide reforming of methane. Applied Catalysis B, 2013, vol. 136–137, pp. 308–316. DOI: 10.1016/j.apcatb.2013.02.019.
  26. Chalupka K.A., Jozwiak W.K., Rynkowski J. et al. Partial oxidation of methane on NixAlBEA and NixSiBEA zeolite catalysts: Remarkable effect of preparation procedure and Ni content. Applied Catalysis B, 2014, vol. 146, pp. 227–236.
  27. Isaeva E.A., Loktev A.S., Mukhin I.E., Bespalov A.S., Buznik V.M., Dedov A.G. New catalysts based on highly porous ceramic materials for processing gas and renewable raw materials in chemical oil refining products. Abstracts of 14th conf. «Physicochemical problems of renewable energy». Chernogolovka, 2018, p. 105.
  28. Voloshin Y.Z., Belaya I.G., Krämer R. Cage metal complexes: clathrochelates revisited. Heidelberg: Springer, 2017, 467 p. DOI: 10.1007/978-3-319-56420-3.
  29. Dedov A.G., Voloshin Y.Z., Loktev A.S., Buznik V.M., Belov A.S., Bespalov A.S. New heterogeneous catalytic system based on highly porous ceramic materials modified with immobilized d-metal cage complexes for H2 production from CH4. Mendeleev Communications, 2019, vol. 29, no. 6, pp. 669–671. DOI: 10.1016/j.mencom.2019.11.022.
  30. Dedov A.G., Loktev A.S., Ivanov V.K. et al. Selective oxidation of methane into syngas: catalysts based on cobalt and nickel. Doklady akademii nauk, 2015, vol. 461, no. 4, pp. 426–432.